Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream     

Sam J. Leuthold  Stephanie A. Ewing  Robert A. Payn  Florence R. Miller  Stephan G. Custer 《水文研究》2021,35(2):e14029

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   

The brecciated texture of polymict eucrites: Petrographic investigations of unequilibrated meteorites from the Antarctic Yamato collection     

Christian Vollmer  Stella Rombeck  Julia Roszjar  Adam R. Sarafian  Stephan Klemme 《Meteoritics & planetary science》2020,55(3):558-574

We report on the petrography and mineralogy of five Yamato polymict eucrites to better constrain the formation and alteration of crustal material on differentiated asteroids. Each sample consists of different lithic clasts that altogether form four dominant textures and therefore appear to originate from closely related petrological areas within Vesta′s crust. The textures range from subophitic to brecciated, porphyritic, and quench‐textured, that differ from section to section. Comparison with literature data for these samples is therefore difficult, which stresses that polymict eucrites are extremely complex in their petrography and investigation of only one thick section may not be representative for the host rock. We also show that sample Y‐793548 consists of more than one lithic unit and must therefore be classified as polymict instead of monomict. The variety and nature of lithic textures in the investigated Yamato meteorites indicate shock events, intense post‐magmatic thermal annealing, and secondary alteration. These postmagmatic features occur in different intensities, varying from clast to clast or among coexisting mineral fragments on a small, local scale. Several clasts within the eucrites studied have been modified by late‐stage alteration processes that caused deposition of Fe‐rich olivine and Fe enrichment along cracks crosscutting pyroxene crystals. However, formation of these secondary phases seems to be independent of the degree of thermal metamorphism observed within every type of clast, which would support a late‐stage metasomatism model for their formation.  相似文献   

“Comet‐tail” ejecta streaks: A predicted cratering landform unique to Titan     

Ralph D. Lorenz 《Meteoritics & planetary science》2004,39(4):617-623

Abstract— A model for an impact ejecta landform peculiar to Saturn's moon Titan is presented. Expansion of the ejecta plume from moderate‐sized craters is constrained by Titan's thick atmosphere. Much of the plume is collimated along the incoming bolide's trajectory, as was observed for plumes from impacts on Jupiter of P/Shoemaker‐Levy‐9, but is retained as a linear, diagonal ejecta cloud, unlike on Venus where the plume “blows out.” On Titan, the blowout is suppressed because the vertically‐extended atmosphere requires a long wake to reach the vacuum of space, and the modest impact velocities mean plume expansion along the wake is slow enough to allow the wake to close off. Beyond the immediate ejecta blanket around the crater, distal ejecta is released into the atmosphere from an oblique line source: this material is winnowed by the zonal wind field to form streaks, with coarse radar‐bright particles transported less far than fine radar‐dark material. Thus, the ejecta form two distinct streaks faintly reminiscent of dual comet tails, a sharply W‐E radar‐dark one, and a less swept and sometimes comma‐shaped radar‐bright one.  相似文献   

40Ar-39Ar dating of the H3 chondrite Sainte Rose     

Thomas Stephan  Elmar K. Jessberger 《Meteoritics & planetary science》1992,27(5):580-584

Abstract— A whole rock sample from the H3 chondrite Sainte Rose, which was discovered in 1983, was dated with the ⁴⁰Ar-³⁹Ar technique. From the K/Ca spectrum and from an analysis of the ³⁹Ar recoil effect we conclude that this meteorite has at least two distinguishable K-carriers: a low temperature, high-K/Ca, fine-grained carrier with a typical grain size of about 2 μm and a high temperature, low-K/Ca, more coarse-grained carrier. The K-Ar clocks of both were started 4.40 ± 0.01 Ga ago.  相似文献   

Radiocarbon on Titan     

Ralph D. Lorenz  A. J. Timothy Jull  Timothy D. Swindle  Jonathan I. Lunine 《Meteoritics & planetary science》2002,37(6):867-874

Abstract— We explore the likely production and fate of ¹⁴C in the thick nitrogen atmosphere of Saturn's moon Titan and investigate the constraints that measurements of ¹⁴C might place on Titan's photochemical, atmospheric transport and surface‐atmosphere interaction processes. Titan's atmosphere is thick enough that cosmic‐ray flux limits the production of ¹⁴C: absence of a strong magnetic field and the increased distance from the Sun suggest production rates of ?9 atom/cm²/s, ?4x higher than Earth. The fate and detectability of ¹⁴C depends on the chemical species into which it is incorporated: as methane it would be hopelessly diluted even in only the atmosphere. However, in the more likely case that the ¹⁴C attaches to the haze that rains out onto the surface (as tholin, HCN or acetylene and their polymers), haze in the atmosphere or recently deposited on the surface would be quite radioactive. Such radioactivity may lead to a significant enhancement in the electrical conductivity of the atmosphere which will be measured by the Huygens probe. Measurements with simple detectors on future missions could place useful constraints on the mass deposition rates of photochemical material on the surface and identify locations where surface deposits of such material are “freshest”.  相似文献   

Effects of natural attenuation processes on groundwater contamination caused by abandoned waste sites in Berlin     

Helmut Kerndorff  Stephan Kühn  Thomas Minden  Dagmar Orlikowski  Thomas Struppe 《Environmental Geology》2008,55(2):291-301

The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones.  相似文献   

Coupled redox transformations of catechol and cerium at the surface of a cerium(III) phosphate mineral     

Javiera Cervini-Silva  Benjamin Gilbert  Sirine Fakra  Stephan Friedlich  Jillian Banfield   《Geochimica et cosmochimica acta》2008,72(10):2454-2464

Highly insoluble Ce-bearing phosphate minerals form by weathering of apatite [Ca₅(PO₄)₃.(OH,F,Cl)], and are important phosphorous repositories in soils. Although these phases can be dissolved via biologically-mediated pathways, the dissolution mechanisms are poorly understood. In this paper we report spectroscopic evidence to support coupling of redox transformations of organic carbon and cerium during the reaction of rhabdophane (CePO₄·H₂O) and catechol, a ubiquitous biogenic compound, at pH 5. Results show that the oxic–anoxic conditions influence the mineral dissolution behavior. Under anoxic conditions, the release of P and Ce occurs stoichiometrically. In contrast, under oxic conditions, the mineral dissolution behavior is incongruent, with dissolving Ce³⁺ ions oxidizing to CeO₂. Reaction product analysis shows the formation of CO₂, polymeric C, and oxalate and malate. The presence of more complex forms of organic carbon was also confirmed. Near edge X-ray absorption fine structure spectroscopy measurements at Ce-M_4,5 and C-K absorption edges on reacted CePO₄·H₂O samples in the absence or presence of catechol and dissolved oxygen confirm that (1) the mineral surface converts to the oxide during this reaction, while full oxidation is limited to the near-surface region only; (2) the Ce valence remains unchanged when the reaction between CePO₄·H₂O and O₂ but in the absence of catechol. Carbon K-edge spectra acquired from rhabdophane reacted with catechol under oxic conditions show spectral features before and after reaction that are considerably different from catechol, indicating the formation of more complex organic molecules. Decreases in intensity of characteristic catechol peaks are accompanied by the appearance of new π^* resonances due to carbon in carboxyl (ca. 288.5 eV) and carbonyl (ca. 289.3 eV) groups, and the development of broad structure in the σ^* region characteristic of aliphatic carbon. Evolution of the C K-edge spectra is consistent with aromatic-ring cleavage and polymerization. These results further substantiate that the presence of catechol, O₂ (aq) causes both the oxidation of structural Ce³⁺ and the transformation of catechol to more complex organic molecules. Scanning Transmission X-Ray Microscopy measurements at the C K and Ce M_4,5 edges indicate three dominant organic species, varying in complexity and association with the inorganic phase. Untransformed catechol is loosely associated with CeO₂, whereas more complex organic molecules that exhibit lower aromaticity and stronger CO π^* resonances of carboxyl-C and carbonyl-C groups are only found in association with the grains. These results further serve as basis to postulate that, in the presence of O₂, CeO₂ can mediate the oxidative polymerization of catechol to form higher molecular weight polymers. The present work provides evidence for a pathway of biologically-induced, non-enzymatic oxidation of cerium and formation of small CeO₂ particles at room temperature. These findings may have implications for carbon cycling in natural and cerium-contaminated soils and aqueous environments.  相似文献   

Tidal inundation mapping under enhanced land subsidence in Semarang,Central Java Indonesia   总被引：3，自引：0，他引：3  

Muh Aris Marfai  Lorenz King 《Natural Hazards》2008,44(1):93-109

Tidal inundation by high tide under enhanced land subsidence is a damaging phenomenon and a major threat to the Semarang urban area in Indonesia. It impacts on economic activities, as well as the cost of an emergency program and causes interruption of pubic services, danger of infectious diseases and injury to human lives. This study examines a spatial analysis tool on the GIS-raster system for the tidal inundation mapping based on the subsidence-benchmark data and modified detail digital elevation model. Neighborhood operation and iteration model as a spatial analysis tool have been applied in order to calculate the encroachment of the tidal inundation on the coastal area. The resulting map shows that the tidal flood spreads to the lowland area and causes the inundation of coastal settlement, infrastructure, as well as productive agricultural land, i.e., the fish-pond area. The monitoring of the vulnerable area due to the tidal inundation under the scenario of extended land subsidence plays an important role in long-term coastal zone management in Semarang.  相似文献   

Defect properties of albite     

Stephan Lowitzer  Dan J. Wilson  Björn Winkler  Victor Milman  Julian D. Gale 《Physics and Chemistry of Minerals》2008,35(3):129-135

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.  相似文献   

Die Intensitätsverteilung der Himmelsstrahlung während der totalen Sonnenfinsternis Am 15. 2. 1961 auf Grund photographischer Messungen     

Dieter Lorenz 《Pure and Applied Geophysics》1962,53(1):143-158

Zusammenfassung Es wird über eine photographische Methode berichtet, die gestattet, die Verteilung der Himmelsstrahlung zu bestimmen. Der Himmel wird mit einer Weitwinkelkamera photographiert und die Aufnahmen werden mit einem Photometer ausgewertet. Über einen Graukeil, der auf das gleiche filmmaterial aufbelichtet und mit den Aufnahmen zusammen entwickelt wird, lassen sich die mit dem Photometer ermittelten Schwärzungswerte in (relative) Intensitätswerte der Himmelsstrahlung umrechnen. Der durch das Photoobjektiv bedingte Helligkeitsabfall von der Bildmitte aus nach den Bildrändern zu wird experimentell ermittelt und als Korrektur an den Meßwerten angebracht. Die Intensitätsverteilung der Himmelsstrahlung während der totalen Sonnenfinsternis am 15. Februar 1961 in Viareggio (Norditalien), am Abend zuvor und am Folgetag wird wiedergegeben und diskutiert. Während der totalen Verfinsterung spiegelt sich insbesondere die Wanderung des Mondschattens relativ zum Beobachtungsort in den Darstellungen wieder. Während der partiellen Verfinsterung ist dagegen die relative Helligkeitsverteilung praktisch die gleiche wie bei unverfinsterter Sonne.

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Summary A photographic method is described which permits to determinate the distribution of the sky radiation. The sky is photographed by a wide angle camera and the resulting pictures are evaluated by a photometer. A photometric step wedge copied on a film of the same type and number is developed together with the pictures. Then the density values measured by the photometer can be transformed into (relative) intensity values of the sky radiation. The decrease in brightness from the centre of the picture to the rim caused by the photographic lens is determined experimentally and is taken into account as a correction to the density values. The distribution of intensity of the sky radiation in Viareggio (North Italy) during the total eclipse of the sun on the 15th of february 1961, on the previous evening and on the following day are shown and discussed. During the total eclipse especially the migration of the moon's shadow in relation to the observation point is clearly defined. During the partial eclipse, however, practically the same relative distribution of sky radiation is found as without eclipse.

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